Titration

There is a variety of different color indicators available for determining the endpoint of a titration (Table 1). The best indictor to use for a titration depends upon the pH at the equivalence point. For example, if the pH at the equivalence point were 9.2, both thymol blue a phenolphthalein would be suitable indicators. The pH at the equivalence point is dependent upon the acid and base strength of the titrant and the solution being titrated. For example, when titrating a strong acid with a strong base, the pH at the equivalence point can be significantly different than the equivalence point of a titration between a weak acid and a strong base. Figure 1 illustrates an acid-base titration curve for the titration of 0.100 M HCl (a strong acid), with NaOH (a strong base).

 

Indicator

pH Range

color in acid form

color in base form

Methyl Violet

0.0 -1.6

yellow

bluish-violet

Thymol Blue

1.2 - 2.8

red

yellow

Methyl Orange

3.1 - 4.4

red

orange

Methyl Red

4.2 - 6.3

red

yellow

Thymol Blue

8.0 - 9.6

yellow

blue

Phenolphthalein

8.3 - 10.0

colorless

red

Table 1

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